Exotic Matter is used for a bunch of missions that will allow blueprints for an Exotic Cannon, Exotic Barrier and Exotic Lab (best of the 3). Additionally, you can also use it to get a mission that will allow you to 'flush' your NPC list.
Once the stuff accumulates into the billions it should collapse under it's own mass and form a new exotic planet for us. Would be the best use for it. :p
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